Thanks GtarLover, I was actually thinking of that today. Great point, wasn't sure if I could turn off the 'power amp sim' of the Kemper but will check the manual for how to do it. (P.s. GtarLover, could you just confirm that i've got the signal chain correct?!)
With that consideration in mind though I think i'll look into buying a separate (or retro-fit) solid state power amp so that the direct amp profiles are 100% accurate rather than half herbert (though i'll obviously check that out too!)
Thanks for all the help guys!