For high gain, at least 220uf on the mains.
On Marshall style chassis with the 6 cap cans, I've done 2 x 500uf JJ can caps in series ( 250uf ) with excellent results.
I got the idea from Suhr, but it's also a Jose thing as well.
PI is usually 100uf.
Then I'll start with 32uf on all the pre nodes and dial in the feel with the screen filtering, sometimes going back and adjusting the pre nodes up or down.
Negative feedback comes into play here as well, for feel and tone, as do voltages.
There's a reason SLO's and Wizards sound as huge as they do, and it's in the power supply design. Different approaches, but same big punchy room-filling result.
At the base level, all a guitar amp is doing is modulating the DC power supply to produce an AC output.
The power supply IS the amp.
YMMV