Update to the update:
The G-2 pedal DOES in fact have a buffer in it. @psychodave this is probably why the chain does not like a buffer engaged....there already is one!
I am going to test my sound with and without the buffer to see which I prefer.
Everything is a learning process....but that's what makes it fun!
I removed that pedal from the chain and powered down my board.
Guitar still sounds awesome, like I just have one solid cable running straight to my amp.
Glad to understand what is going on finally.